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McCormack reaction
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McCormack reaction : ウィキペディア英語版
McCormack reaction
The McCormack reaction is a method for the synthesis of organophosphorus compounds. In this reaction a 1,3-diene and a source of R2P+ are combined to give phospholenium cation. The reaction is named after W. B. McCormack, a research chemist at duPont.
An illustrative reaction involves phenyldichlorophosphine and isoprene:
:320 px
The reaction proceeds via an pericyclic ()-process. The resulting derivatives can be hydrolyzed to give the phosphine oxide. Dehydrohalogenation gives the phosphole.〔Handbook of organophosphorus chemistry by Robert Engel, CRC Press, 1992. ISBN 0-8247-8733-1.〕
==References==


抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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